Advantages of organic halogen bonding for halide recognition

Nicholas B. Wageling; George F. Neuhaus; Ariana M. Rose; Daniel A. Decato; Orion B. Berryman

doi:10.1080/10610278.2015.1118101

Advantages of organic halogen bonding for halide recognition

Nicholas B. Wageling, George F. Neuhaus, Ariana M. Rose, Daniel A. Decato, Orion B. Berryman

Chemistry

University of Montana

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The synthesis of a bidentate halogen bonding receptor and a nearly isostructural hydrogen bonding analogue is described. Crystal structures reveal the interactions of each receptor with anions in the solid state, while NMR titrations elucidate bidentate binding and association constants in solution. Of the two, the halogen bonding receptor demonstrates stronger, water resistant halide binding in competitive solvents.

Original language	English
Pages (from-to)	665-672
Number of pages	8
Journal	Supramolecular Chemistry
Volume	28
Issue number	7-8
DOIs	https://doi.org/10.1080/10610278.2015.1118101
State	Published - Aug 2 2016

Keywords

Halogen bonding
NMR titration
anion recognition

Access to Document

10.1080/10610278.2015.1118101

Cite this

@article{b967ae242dee43ebbd68ac7379edb10b,

title = "Advantages of organic halogen bonding for halide recognition",

abstract = "The synthesis of a bidentate halogen bonding receptor and a nearly isostructural hydrogen bonding analogue is described. Crystal structures reveal the interactions of each receptor with anions in the solid state, while NMR titrations elucidate bidentate binding and association constants in solution. Of the two, the halogen bonding receptor demonstrates stronger, water resistant halide binding in competitive solvents.",

keywords = "Halogen bonding, NMR titration, anion recognition",

author = "Wageling, {Nicholas B.} and Neuhaus, {George F.} and Rose, {Ariana M.} and Decato, {Daniel A.} and Berryman, {Orion B.}",

note = "Publisher Copyright: {\textcopyright} 2015 Informa UK Limited, trading as Taylor & Francis Group.",

year = "2016",

month = aug,

day = "2",

doi = "10.1080/10610278.2015.1118101",

language = "English",

volume = "28",

pages = "665--672",

journal = "Supramolecular Chemistry",

issn = "1061-0278",

publisher = "Taylor and Francis Ltd.",

number = "7-8",

}

TY - JOUR

T1 - Advantages of organic halogen bonding for halide recognition

AU - Wageling, Nicholas B.

AU - Neuhaus, George F.

AU - Rose, Ariana M.

AU - Decato, Daniel A.

AU - Berryman, Orion B.

PY - 2016/8/2

Y1 - 2016/8/2

N2 - The synthesis of a bidentate halogen bonding receptor and a nearly isostructural hydrogen bonding analogue is described. Crystal structures reveal the interactions of each receptor with anions in the solid state, while NMR titrations elucidate bidentate binding and association constants in solution. Of the two, the halogen bonding receptor demonstrates stronger, water resistant halide binding in competitive solvents.

AB - The synthesis of a bidentate halogen bonding receptor and a nearly isostructural hydrogen bonding analogue is described. Crystal structures reveal the interactions of each receptor with anions in the solid state, while NMR titrations elucidate bidentate binding and association constants in solution. Of the two, the halogen bonding receptor demonstrates stronger, water resistant halide binding in competitive solvents.

KW - Halogen bonding

KW - NMR titration

KW - anion recognition

UR - http://www.scopus.com/inward/record.url?scp=84949562349&partnerID=8YFLogxK

U2 - 10.1080/10610278.2015.1118101

DO - 10.1080/10610278.2015.1118101

M3 - Article

AN - SCOPUS:84949562349

SN - 1061-0278

VL - 28

SP - 665

EP - 672

JO - Supramolecular Chemistry

JF - Supramolecular Chemistry

IS - 7-8

ER -

Advantages of organic halogen bonding for halide recognition

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this