Advantages of organic halogen bonding for halide recognition

Nicholas B. Wageling, George F. Neuhaus, Ariana M. Rose, Daniel A. Decato, Orion B. Berryman

Research output: Contribution to journalArticlepeer-review

Abstract

The synthesis of a bidentate halogen bonding receptor and a nearly isostructural hydrogen bonding analogue is described. Crystal structures reveal the interactions of each receptor with anions in the solid state, while NMR titrations elucidate bidentate binding and association constants in solution. Of the two, the halogen bonding receptor demonstrates stronger, water resistant halide binding in competitive solvents.

Original languageEnglish
Pages (from-to)665-672
Number of pages8
JournalSupramolecular Chemistry
Volume28
Issue number7-8
DOIs
StatePublished - Aug 2 2016

Keywords

  • Halogen bonding
  • NMR titration
  • anion recognition

Fingerprint

Dive into the research topics of 'Advantages of organic halogen bonding for halide recognition'. Together they form a unique fingerprint.

Cite this