Advantages of organic halogen bonding for halide recognition

Nicholas B. Wageling; George F. Neuhaus; Ariana M. Rose; Daniel A. Decato; Orion B. Berryman

doi:10.1080/10610278.2015.1118101

Advantages of organic halogen bonding for halide recognition

Nicholas B. Wageling
, George F. Neuhaus
, Ariana M. Rose
, Daniel A. Decato
, Orion B. Berryman

Chemistry and Biochemistry

University of Montana

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The synthesis of a bidentate halogen bonding receptor and a nearly isostructural hydrogen bonding analogue is described. Crystal structures reveal the interactions of each receptor with anions in the solid state, while NMR titrations elucidate bidentate binding and association constants in solution. Of the two, the halogen bonding receptor demonstrates stronger, water resistant halide binding in competitive solvents.

Original language	English
Pages (from-to)	665-672
Number of pages	8
Journal	Supramolecular Chemistry
Volume	28
Issue number	7-8
DOIs	https://doi.org/10.1080/10610278.2015.1118101
State	Published - Aug 2 2016

Funding

This work was financially supported by the Center for Biomolecular Structure and Dynamics CoBRE [grant number NIGMS P20GM103546]; National Science Foundation (NSF)-MRI [grant number CHE – 1337908]; Montana University System MREDI [grant number 51030-MUSRI2015-02] and the University of Montana (UM). Funding for N. W. was provided by the UM CBSD Fellowship programme (NIGMS P20GM103546)

Funders	Funder number
Center for Biomolecular Structure and Dynamics
51030-MUSRI2015-02
P20GM103546
CHE – 1337908

Keywords

Halogen bonding
NMR titration
anion recognition

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10.1080/10610278.2015.1118101

Cite this

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abstract = "The synthesis of a bidentate halogen bonding receptor and a nearly isostructural hydrogen bonding analogue is described. Crystal structures reveal the interactions of each receptor with anions in the solid state, while NMR titrations elucidate bidentate binding and association constants in solution. Of the two, the halogen bonding receptor demonstrates stronger, water resistant halide binding in competitive solvents.",

keywords = "Halogen bonding, NMR titration, anion recognition",

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AU - Wageling, Nicholas B.

AU - Neuhaus, George F.

AU - Rose, Ariana M.

AU - Decato, Daniel A.

AU - Berryman, Orion B.

PY - 2016/8/2

Y1 - 2016/8/2

N2 - The synthesis of a bidentate halogen bonding receptor and a nearly isostructural hydrogen bonding analogue is described. Crystal structures reveal the interactions of each receptor with anions in the solid state, while NMR titrations elucidate bidentate binding and association constants in solution. Of the two, the halogen bonding receptor demonstrates stronger, water resistant halide binding in competitive solvents.

AB - The synthesis of a bidentate halogen bonding receptor and a nearly isostructural hydrogen bonding analogue is described. Crystal structures reveal the interactions of each receptor with anions in the solid state, while NMR titrations elucidate bidentate binding and association constants in solution. Of the two, the halogen bonding receptor demonstrates stronger, water resistant halide binding in competitive solvents.

KW - Halogen bonding

KW - NMR titration

KW - anion recognition

UR - https://www.scopus.com/pages/publications/84949562349

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DO - 10.1080/10610278.2015.1118101

M3 - Article

AN - SCOPUS:84949562349

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JF - Supramolecular Chemistry

IS - 7-8

ER -

Advantages of organic halogen bonding for halide recognition

Abstract

Funding

Keywords

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