Cyclobutadieneiron tricarbonyl carboxylic acids: Synthesis and acidity

D. Stierle; E. R. Biehl; P. C. Reeves

doi:10.1016/S0022-328X(00)81495-3

Cyclobutadieneiron tricarbonyl carboxylic acids: Synthesis and acidity

D. Stierle
, E. R. Biehl
, P. C. Reeves

Southern Methodist University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Two carboxylic acid derivatives of the cyclobutadieneiron tricarbonyl (I) system have been synthesized and their pK_a values determined. It appears that I tends to be electron withdrawing by induction and electron releasing by resonance.

Original language	English
Pages (from-to)	221-225
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	72
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)81495-3
State	Published - Jun 11 1974

Funding

The authors thank Dr. Rowland Pettit for his generous assistance and the Robert A. Welch Foundation for financial support.

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10.1016/S0022-328X(00)81495-3

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@article{a5b38a7939c24435bf4977fc56a11b2f,

title = "Cyclobutadieneiron tricarbonyl carboxylic acids: Synthesis and acidity",

abstract = "Two carboxylic acid derivatives of the cyclobutadieneiron tricarbonyl (I) system have been synthesized and their pKa values determined. It appears that I tends to be electron withdrawing by induction and electron releasing by resonance.",

author = "D. Stierle and Biehl, \{E. R.\} and Reeves, \{P. C.\}",

note = "Funding Information: The authors thank Dr. Rowland Pettit for his generous assistance and the Robert A. Welch Foundation for financial support.",

year = "1974",

month = jun,

day = "11",

doi = "10.1016/S0022-328X(00)81495-3",

language = "English",

volume = "72",

pages = "221--225",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Cyclobutadieneiron tricarbonyl carboxylic acids

T2 - Synthesis and acidity

AU - Stierle, D.

AU - Biehl, E. R.

AU - Reeves, P. C.

N1 - Funding Information: The authors thank Dr. Rowland Pettit for his generous assistance and the Robert A. Welch Foundation for financial support.

PY - 1974/6/11

Y1 - 1974/6/11

N2 - Two carboxylic acid derivatives of the cyclobutadieneiron tricarbonyl (I) system have been synthesized and their pKa values determined. It appears that I tends to be electron withdrawing by induction and electron releasing by resonance.

AB - Two carboxylic acid derivatives of the cyclobutadieneiron tricarbonyl (I) system have been synthesized and their pKa values determined. It appears that I tends to be electron withdrawing by induction and electron releasing by resonance.

UR - https://www.scopus.com/pages/publications/0345557142

U2 - 10.1016/S0022-328X(00)81495-3

DO - 10.1016/S0022-328X(00)81495-3

M3 - Article

AN - SCOPUS:0345557142

SN - 0022-328X

VL - 72

SP - 221

EP - 225

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Cyclobutadieneiron tricarbonyl carboxylic acids: Synthesis and acidity

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