Depolarized Rayleigh scattering study of pyrimidine

Scott L. Whittenburg; Vinod K. Jain; Stuart J. McKinnon

doi:10.1016/0167-7322(90)80073-S

Depolarized Rayleigh scattering study of pyrimidine

Scott L. Whittenburg, Vinod K. Jain, Stuart J. McKinnon

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Abstract

The depolarized Rayleigh spectrum from pyrimidine has been obtained from 296K to 395K. The spectra do not display a shear wave dip at zero frequency due to translation-rotation coupling. The Stokes - Einstein - Debye plot of the reorientation time versus viscosity/temperature displays a slightly non-linear relation. The light scattering orientation pair correlation factor obtained by comparing the depolarized Rayleigh reorientation to the single particle time from NMR for pyrimidine is 2.3. This value is compared to other azobenzenes.

Original language	English
Pages (from-to)	161-169
Number of pages	9
Journal	Journal of Molecular Liquids
Volume	47
Issue number	1-3
DOIs	https://doi.org/10.1016/0167-7322(90)80073-S
State	Published - Nov 1990

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title = "Depolarized Rayleigh scattering study of pyrimidine",

abstract = "The depolarized Rayleigh spectrum from pyrimidine has been obtained from 296K to 395K. The spectra do not display a shear wave dip at zero frequency due to translation-rotation coupling. The Stokes - Einstein - Debye plot of the reorientation time versus viscosity/temperature displays a slightly non-linear relation. The light scattering orientation pair correlation factor obtained by comparing the depolarized Rayleigh reorientation to the single particle time from NMR for pyrimidine is 2.3. This value is compared to other azobenzenes.",

author = "Whittenburg, {Scott L.} and Jain, {Vinod K.} and McKinnon, {Stuart J.}",

year = "1990",

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AU - Whittenburg, Scott L.

AU - Jain, Vinod K.

AU - McKinnon, Stuart J.

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N2 - The depolarized Rayleigh spectrum from pyrimidine has been obtained from 296K to 395K. The spectra do not display a shear wave dip at zero frequency due to translation-rotation coupling. The Stokes - Einstein - Debye plot of the reorientation time versus viscosity/temperature displays a slightly non-linear relation. The light scattering orientation pair correlation factor obtained by comparing the depolarized Rayleigh reorientation to the single particle time from NMR for pyrimidine is 2.3. This value is compared to other azobenzenes.

AB - The depolarized Rayleigh spectrum from pyrimidine has been obtained from 296K to 395K. The spectra do not display a shear wave dip at zero frequency due to translation-rotation coupling. The Stokes - Einstein - Debye plot of the reorientation time versus viscosity/temperature displays a slightly non-linear relation. The light scattering orientation pair correlation factor obtained by comparing the depolarized Rayleigh reorientation to the single particle time from NMR for pyrimidine is 2.3. This value is compared to other azobenzenes.

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U2 - 10.1016/0167-7322(90)80073-S

DO - 10.1016/0167-7322(90)80073-S

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AN - SCOPUS:0025517078

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VL - 47

SP - 161

EP - 169

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

IS - 1-3

ER -

Depolarized Rayleigh scattering study of pyrimidine

Abstract

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