Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-dihydropyridine-3,5- dicarboxylate

Scott A. Steiger, Anthony J. Monacelli, Chun Li, Janet L. Hunting, Nicholas R. Natale

Research output: Contribution to journalArticlepeer-review

Abstract

The title compound, C25H27NO4, has a flattened dihydropyridine ring. The benzene and phenyl rings are synclinal to one another, forming a dihedral angle of 49.82 (8)̊; the axis of the biphenyl rings makes an 81.05 (9)- angle to the plane of the dihydropyridine ring. In the crystal, N-H⋯O hydrogen bonds link the molecules into chain motifs running along the a-axis direction. The chains are cross-linked by C-H⋯O interactions, forming sheet motifs running slightly off the (110) plane, together with an intermolecular interaction between head-to tail biphenyl groups, thus making the whole crystal packing a three-dimensional network. Intramolecular C-H⋯O hydrogen bonds are also observed.

Original languageEnglish
Pages (from-to)o791-o792
JournalActa Crystallographica Section E: Structure Reports Online
Volume70
Issue number7
DOIs
StatePublished - Jul 2014

Keywords

  • Data-to-parameter ratio = 17.0
  • Mean σ(C-C) = 0.003 Å
  • R factor = 0.062
  • Single-crystal X-ray study
  • T = 100 K
  • WR factor = 0.149

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