TY - JOUR
T1 - Diethyl 4-(biphenyl-4-yl)-2,6-dimethyl-1,4-dihydropyridine-3,5- dicarboxylate
AU - Steiger, Scott A.
AU - Monacelli, Anthony J.
AU - Li, Chun
AU - Hunting, Janet L.
AU - Natale, Nicholas R.
PY - 2014/7
Y1 - 2014/7
N2 - The title compound, C25H27NO4, has a flattened dihydropyridine ring. The benzene and phenyl rings are synclinal to one another, forming a dihedral angle of 49.82 (8)̊; the axis of the biphenyl rings makes an 81.05 (9)- angle to the plane of the dihydropyridine ring. In the crystal, N-H⋯O hydrogen bonds link the molecules into chain motifs running along the a-axis direction. The chains are cross-linked by C-H⋯O interactions, forming sheet motifs running slightly off the (110) plane, together with an intermolecular interaction between head-to tail biphenyl groups, thus making the whole crystal packing a three-dimensional network. Intramolecular C-H⋯O hydrogen bonds are also observed.
AB - The title compound, C25H27NO4, has a flattened dihydropyridine ring. The benzene and phenyl rings are synclinal to one another, forming a dihedral angle of 49.82 (8)̊; the axis of the biphenyl rings makes an 81.05 (9)- angle to the plane of the dihydropyridine ring. In the crystal, N-H⋯O hydrogen bonds link the molecules into chain motifs running along the a-axis direction. The chains are cross-linked by C-H⋯O interactions, forming sheet motifs running slightly off the (110) plane, together with an intermolecular interaction between head-to tail biphenyl groups, thus making the whole crystal packing a three-dimensional network. Intramolecular C-H⋯O hydrogen bonds are also observed.
KW - Data-to-parameter ratio = 17.0
KW - Mean σ(C-C) = 0.003 Å
KW - R factor = 0.062
KW - Single-crystal X-ray study
KW - T = 100 K
KW - WR factor = 0.149
UR - http://www.scopus.com/inward/record.url?scp=84904154438&partnerID=8YFLogxK
U2 - 10.1107/S1600536814013294
DO - 10.1107/S1600536814013294
M3 - Article
AN - SCOPUS:84904154438
SN - 1600-5368
VL - 70
SP - o791-o792
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -