Abstract
The title compound, C25H27NO4, has a flattened dihydropyridine ring. The benzene and phenyl rings are synclinal to one another, forming a dihedral angle of 49.82 (8)̊; the axis of the biphenyl rings makes an 81.05 (9)- angle to the plane of the dihydropyridine ring. In the crystal, N-H⋯O hydrogen bonds link the molecules into chain motifs running along the a-axis direction. The chains are cross-linked by C-H⋯O interactions, forming sheet motifs running slightly off the (110) plane, together with an intermolecular interaction between head-to tail biphenyl groups, thus making the whole crystal packing a three-dimensional network. Intramolecular C-H⋯O hydrogen bonds are also observed.
| Original language | English |
|---|---|
| Pages (from-to) | o791-o792 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 70 |
| Issue number | 7 |
| DOIs | |
| State | Published - Jul 2014 |
Keywords
- Data-to-parameter ratio = 17.0
- Mean σ(C-C) = 0.003 Å
- R factor = 0.062
- Single-crystal X-ray study
- T = 100 K
- WR factor = 0.149
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