Ethyl 3-(10-chloroanthracenyl)-5-(1-phenyl-2-hydroxyethenyl)isoxazole-4-carboxylate: An enol produced by Dess-Martin oxidation

Chun Li; Brendan Twamley; Nicholas R. Natale

doi:10.1107/S1600536806002698

Ethyl 3-(10-chloroanthracenyl)-5-(1-phenyl-2-hydroxyethenyl)isoxazole-4-carboxylate: An enol produced by Dess-Martin oxidation

Chun Li
, Brendan Twamley
, Nicholas R. Natale

University of Idaho

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The title compound, C₂₈H₂₀ClNO₄, is a very stable enol produced by a Dess-Martin oxidation, not the expected ketone. The enol form is stabilized by intramolecular hydrogen bonding and the molecules associate into dimers via weak C-H⋯N hydrogen bonding.

Original language	English
Pages (from-to)	o854-o856
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	2
DOIs	https://doi.org/10.1107/S1600536806002698
State	Published - Feb 1 2006

Access to Document

10.1107/S1600536806002698

Cite this

@article{d501b70297764c5caa256fe10ea5633c,

title = "Ethyl 3-(10-chloroanthracenyl)-5-(1-phenyl-2-hydroxyethenyl)isoxazole-4-carboxylate: An enol produced by Dess-Martin oxidation",

abstract = "The title compound, C28H20ClNO4, is a very stable enol produced by a Dess-Martin oxidation, not the expected ketone. The enol form is stabilized by intramolecular hydrogen bonding and the molecules associate into dimers via weak C-H⋯N hydrogen bonding.",

author = "Chun Li and Brendan Twamley and Natale, \{Nicholas R.\}",

year = "2006",

month = feb,

day = "1",

doi = "10.1107/S1600536806002698",

language = "English",

volume = "62",

pages = "o854--o856",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "2",

}

TY - JOUR

T1 - Ethyl 3-(10-chloroanthracenyl)-5-(1-phenyl-2-hydroxyethenyl)isoxazole-4-carboxylate

T2 - An enol produced by Dess-Martin oxidation

AU - Li, Chun

AU - Twamley, Brendan

AU - Natale, Nicholas R.

PY - 2006/2/1

Y1 - 2006/2/1

N2 - The title compound, C28H20ClNO4, is a very stable enol produced by a Dess-Martin oxidation, not the expected ketone. The enol form is stabilized by intramolecular hydrogen bonding and the molecules associate into dimers via weak C-H⋯N hydrogen bonding.

AB - The title compound, C28H20ClNO4, is a very stable enol produced by a Dess-Martin oxidation, not the expected ketone. The enol form is stabilized by intramolecular hydrogen bonding and the molecules associate into dimers via weak C-H⋯N hydrogen bonding.

UR - https://www.scopus.com/pages/publications/33644765683

U2 - 10.1107/S1600536806002698

DO - 10.1107/S1600536806002698

M3 - Article

AN - SCOPUS:33644765683

SN - 1600-5368

VL - 62

SP - o854-o856

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 2

ER -

Ethyl 3-(10-chloroanthracenyl)-5-(1-phenyl-2-hydroxyethenyl)isoxazole-4-carboxylate: An enol produced by Dess-Martin oxidation

Abstract

Access to Document

Other files and links

Fingerprint

Cite this