Ethyl 5-(5-oxo-2,3-dihydro-5H-oxazolo[2,3-a]-isoindol-9b-ylmethyl)-4-(2,5, 5-trimethyl-1,3-dioxan-2-yl)isoxazole-3-carboxylate: The product of a novel synthetic method

Jared Nelson; Brendan Twamley; Nicholas R. Natale

doi:10.1107/S1600536804027655

Ethyl 5-(5-oxo-2,3-dihydro-5H-oxazolo[2,3-a]-isoindol-9b-ylmethyl)-4-(2,5, 5-trimethyl-1,3-dioxan-2-yl)isoxazole-3-carboxylate: The product of a novel synthetic method

Jared Nelson
, Brendan Twamley
, Nicholas R. Natale

University of Idaho

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The title compound, C₂₄H₂₈N₂O₇, is the product of a novel synthetic procedure in which a highly functionalized heterocycle is formed. The crystal packing involves dimers, utilizing non-classical weak C-H⋯O interactions (ca 3.36-3.46 Å) and an antiparallel π-π interaction between two of the pseudo-aromatic isoxazole moieties. These dimers are associated into a three-dimensional network via further nonclassical hydrogen bonding.

Original language	English
Pages (from-to)	o2255-o2257
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	12
DOIs	https://doi.org/10.1107/S1600536804027655
State	Published - Dec 2004

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@article{1c114c4c10a844c5a6ef62b82544ad3d,

title = "Ethyl 5-(5-oxo-2,3-dihydro-5H-oxazolo[2,3-a]-isoindol-9b-ylmethyl)-4-(2,5, 5-trimethyl-1,3-dioxan-2-yl)isoxazole-3-carboxylate: The product of a novel synthetic method",

abstract = "The title compound, C24H28N2O7, is the product of a novel synthetic procedure in which a highly functionalized heterocycle is formed. The crystal packing involves dimers, utilizing non-classical weak C-H⋯O interactions (ca 3.36-3.46 {\AA}) and an antiparallel π-π interaction between two of the pseudo-aromatic isoxazole moieties. These dimers are associated into a three-dimensional network via further nonclassical hydrogen bonding.",

author = "Jared Nelson and Brendan Twamley and Natale, \{Nicholas R.\}",

year = "2004",

month = dec,

doi = "10.1107/S1600536804027655",

language = "English",

volume = "60",

pages = "o2255--o2257",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

}

Ethyl 5-(5-oxo-2,3-dihydro-5H-oxazolo[2,3-a]-isoindol-9b-ylmethyl)-4-(2,5, 5-trimethyl-1,3-dioxan-2-yl)isoxazole-3-carboxylate: The product of a novel synthetic method. / Nelson, Jared; Twamley, Brendan; Natale, Nicholas R.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 12, 12.2004, p. o2255-o2257.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Ethyl 5-(5-oxo-2,3-dihydro-5H-oxazolo[2,3-a]-isoindol-9b-ylmethyl)-4-(2,5, 5-trimethyl-1,3-dioxan-2-yl)isoxazole-3-carboxylate

T2 - The product of a novel synthetic method

AU - Nelson, Jared

AU - Twamley, Brendan

AU - Natale, Nicholas R.

PY - 2004/12

Y1 - 2004/12

N2 - The title compound, C24H28N2O7, is the product of a novel synthetic procedure in which a highly functionalized heterocycle is formed. The crystal packing involves dimers, utilizing non-classical weak C-H⋯O interactions (ca 3.36-3.46 Å) and an antiparallel π-π interaction between two of the pseudo-aromatic isoxazole moieties. These dimers are associated into a three-dimensional network via further nonclassical hydrogen bonding.

AB - The title compound, C24H28N2O7, is the product of a novel synthetic procedure in which a highly functionalized heterocycle is formed. The crystal packing involves dimers, utilizing non-classical weak C-H⋯O interactions (ca 3.36-3.46 Å) and an antiparallel π-π interaction between two of the pseudo-aromatic isoxazole moieties. These dimers are associated into a three-dimensional network via further nonclassical hydrogen bonding.

UR - https://www.scopus.com/pages/publications/18444401443

U2 - 10.1107/S1600536804027655

DO - 10.1107/S1600536804027655

M3 - Article

AN - SCOPUS:18444401443

SN - 1600-5368

VL - 60

SP - o2255-o2257

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Ethyl 5-(5-oxo-2,3-dihydro-5H-oxazolo[2,3-a]-isoindol-9b-ylmethyl)-4-(2,5, 5-trimethyl-1,3-dioxan-2-yl)isoxazole-3-carboxylate: The product of a novel synthetic method

Abstract

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