Identification of the nd Δ and Σ states and the 1,3Φ←←X 3Σg- transition of O2 by resonant multiphoton ionization

Robert J. Yokelson; Robert J. Lipert; William A. Chupka

doi:10.1063/1.463723

Identification of the nd Δ and Σ states and the ^1,3Φ←←X ³Σ_g^- transition of O₂ by resonant multiphoton ionization

Robert J. Yokelson
, Robert J. Lipert
, William A. Chupka

Chemistry and Biochemistry

Yale University

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Spectra of the 3d Rydberg state region of O₂ have been obtained by two-photon resonant ionization of the ground electronic state. By varying the rotational distribution and radiation polarization, all observed bands were identified and attributed to excitation of Σ, Δ, and Φ states. Earlier assignments were corrected. The Δ and Φ assignments are complete while the Σ assignments are so far incomplete.

Original language	English
Pages (from-to)	6144-6152
Number of pages	9
Journal	The Journal of Chemical Physics
Volume	97
Issue number	9
DOIs	https://doi.org/10.1063/1.463723
State	Published - 1992

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title = "Identification of the nd Δ and Σ states and the 1,3Φ←←X 3Σg- transition of O2 by resonant multiphoton ionization",

abstract = "Spectra of the 3d Rydberg state region of O2 have been obtained by two-photon resonant ionization of the ground electronic state. By varying the rotational distribution and radiation polarization, all observed bands were identified and attributed to excitation of Σ, Δ, and Φ states. Earlier assignments were corrected. The Δ and Φ assignments are complete while the Σ assignments are so far incomplete.",

author = "Yokelson, \{Robert J.\} and Lipert, \{Robert J.\} and Chupka, \{William A.\}",

year = "1992",

doi = "10.1063/1.463723",

language = "English",

volume = "97",

pages = "6144--6152",

journal = "The Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

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T1 - Identification of the nd Δ and Σ states and the 1,3Φ←←X 3Σg- transition of O2 by resonant multiphoton ionization

AU - Yokelson, Robert J.

AU - Lipert, Robert J.

AU - Chupka, William A.

PY - 1992

Y1 - 1992

N2 - Spectra of the 3d Rydberg state region of O2 have been obtained by two-photon resonant ionization of the ground electronic state. By varying the rotational distribution and radiation polarization, all observed bands were identified and attributed to excitation of Σ, Δ, and Φ states. Earlier assignments were corrected. The Δ and Φ assignments are complete while the Σ assignments are so far incomplete.

AB - Spectra of the 3d Rydberg state region of O2 have been obtained by two-photon resonant ionization of the ground electronic state. By varying the rotational distribution and radiation polarization, all observed bands were identified and attributed to excitation of Σ, Δ, and Φ states. Earlier assignments were corrected. The Δ and Φ assignments are complete while the Σ assignments are so far incomplete.

UR - https://www.scopus.com/pages/publications/0038736901

U2 - 10.1063/1.463723

DO - 10.1063/1.463723

M3 - Article

AN - SCOPUS:0038736901

SN - 0021-9606

VL - 97

SP - 6144

EP - 6152

JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

IS - 9

ER -

Identification of the nd Δ and Σ states and the ^1,3Φ←←X ³Σ_g^- transition of O₂ by resonant multiphoton ionization

Abstract

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