Metabolites of the Marine Sponge Laxosuberites sp.

Donald B. Stierle; D. John Faulkner

doi:10.1021/jo01312a033

Metabolites of the Marine Sponge Laxosuberites sp.

Donald B. Stierle, D. John Faulkner

University of California at San Diego

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

The marine sponge Laxosuberites sp. contained a mixture of four 5-alkylpyrrole-2-carboxaldehydes 1, (6'Z)-5-(12'-cyano-6'-dodecenyl)pyrrole-2-carboxaldehyde (2), and (6'Z)-5-(23'-cyano-23'-hydroxy-6'-tricosenyl) pyrrole-2-carboxaldehyde (3). The structures of the metabolites were determined by interpretation of spectral data and by chemical degradation. The cyanohydrin 3 is unusually stable to normal isolation and storage procedures.

Original language	English
Pages (from-to)	4980-4982
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	45
Issue number	24
DOIs	https://doi.org/10.1021/jo01312a033
State	Published - Nov 1980

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title = "Metabolites of the Marine Sponge Laxosuberites sp.",

abstract = "The marine sponge Laxosuberites sp. contained a mixture of four 5-alkylpyrrole-2-carboxaldehydes 1, (6'Z)-5-(12'-cyano-6'-dodecenyl)pyrrole-2-carboxaldehyde (2), and (6'Z)-5-(23'-cyano-23'-hydroxy-6'-tricosenyl) pyrrole-2-carboxaldehyde (3). The structures of the metabolites were determined by interpretation of spectral data and by chemical degradation. The cyanohydrin 3 is unusually stable to normal isolation and storage procedures.",

author = "Stierle, {Donald B.} and Faulkner, {D. John}",

year = "1980",

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journal = "Journal of Organic Chemistry",

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AU - Stierle, Donald B.

AU - Faulkner, D. John

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N2 - The marine sponge Laxosuberites sp. contained a mixture of four 5-alkylpyrrole-2-carboxaldehydes 1, (6'Z)-5-(12'-cyano-6'-dodecenyl)pyrrole-2-carboxaldehyde (2), and (6'Z)-5-(23'-cyano-23'-hydroxy-6'-tricosenyl) pyrrole-2-carboxaldehyde (3). The structures of the metabolites were determined by interpretation of spectral data and by chemical degradation. The cyanohydrin 3 is unusually stable to normal isolation and storage procedures.

AB - The marine sponge Laxosuberites sp. contained a mixture of four 5-alkylpyrrole-2-carboxaldehydes 1, (6'Z)-5-(12'-cyano-6'-dodecenyl)pyrrole-2-carboxaldehyde (2), and (6'Z)-5-(23'-cyano-23'-hydroxy-6'-tricosenyl) pyrrole-2-carboxaldehyde (3). The structures of the metabolites were determined by interpretation of spectral data and by chemical degradation. The cyanohydrin 3 is unusually stable to normal isolation and storage procedures.

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 24

ER -

Metabolites of the Marine Sponge Laxosuberites sp.

Abstract

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