Modulating photoswitch performance with halogen, coordinative and hydrogen bonding: A comparison of relative bond strengths

Sofia Lindblad; Daniel Sethio; Orion B. Berryman; Máté Erdélyi

doi:10.1039/d1cc01827b

Modulating photoswitch performance with halogen, coordinative and hydrogen bonding: A comparison of relative bond strengths

Sofia Lindblad, Daniel Sethio, Orion B. Berryman, Máté Erdélyi

Chemistry

Uppsala University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The behavior of an enediyne photoswitch is modulated with halogen bonding, coordinative bonding and hydrogen bonding. Through NMR and computational studies we demonstrate that the relative strength of the secondary bonding directly influences the rate of photoisomerization and the photostationary state.

Original language	English
Pages (from-to)	6261-6263
Number of pages	3
Journal	Chemical Communications
Volume	57
Issue number	51
DOIs	https://doi.org/10.1039/d1cc01827b
State	Published - Jun 28 2021

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10.1039/d1cc01827b

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title = "Modulating photoswitch performance with halogen, coordinative and hydrogen bonding: A comparison of relative bond strengths",

abstract = "The behavior of an enediyne photoswitch is modulated with halogen bonding, coordinative bonding and hydrogen bonding. Through NMR and computational studies we demonstrate that the relative strength of the secondary bonding directly influences the rate of photoisomerization and the photostationary state.",

author = "Sofia Lindblad and Daniel Sethio and Berryman, {Orion B.} and M{\'a}t{\'e} Erd{\'e}lyi",

note = "Publisher Copyright: {\textcopyright} 2021 The Royal Society of Chemistry.",

year = "2021",

month = jun,

day = "28",

doi = "10.1039/d1cc01827b",

language = "English",

volume = "57",

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T1 - Modulating photoswitch performance with halogen, coordinative and hydrogen bonding

T2 - A comparison of relative bond strengths

AU - Lindblad, Sofia

AU - Sethio, Daniel

AU - Berryman, Orion B.

AU - Erdélyi, Máté

PY - 2021/6/28

Y1 - 2021/6/28

N2 - The behavior of an enediyne photoswitch is modulated with halogen bonding, coordinative bonding and hydrogen bonding. Through NMR and computational studies we demonstrate that the relative strength of the secondary bonding directly influences the rate of photoisomerization and the photostationary state.

AB - The behavior of an enediyne photoswitch is modulated with halogen bonding, coordinative bonding and hydrogen bonding. Through NMR and computational studies we demonstrate that the relative strength of the secondary bonding directly influences the rate of photoisomerization and the photostationary state.

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U2 - 10.1039/d1cc01827b

DO - 10.1039/d1cc01827b

M3 - Article

C2 - 34060568

AN - SCOPUS:85108817463

SN - 1359-7345

VL - 57

SP - 6261

EP - 6263

JO - Chemical Communications

JF - Chemical Communications

IS - 51

ER -

Modulating photoswitch performance with halogen, coordinative and hydrogen bonding: A comparison of relative bond strengths

Abstract

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