Abstract
The behavior of an enediyne photoswitch is modulated with halogen bonding, coordinative bonding and hydrogen bonding. Through NMR and computational studies we demonstrate that the relative strength of the secondary bonding directly influences the rate of photoisomerization and the photostationary state.
| Original language | English |
|---|---|
| Pages (from-to) | 6261-6263 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 57 |
| Issue number | 51 |
| DOIs | |
| State | Published - Jun 28 2021 |
Funding
This project made use of the NMR Uppsala infrastructure, which is funded by the Department of Chemistry–BMC and the Disciplinary Domain of Medicine and Pharmacy. We thank Ignacio Fernán-dez Galván for fruitful discussions, and the Swedish Research Council (2020-03431), FORMAS (2017-01173), the Wenner-Gren Foundation (F2020-0003), and the National Science Foundation (CHE-1555324) for financial support. Computations were performed on resources provided by Swedish National Infrastructure for Computing (SNIC) through the National Supercomputer Center (NSC) at Linköping University under Project SNIC2020/5-435.
| Funders | Funder number |
|---|---|
| Department of Chemistry | |
| CHE-1555324 | |
| F2020-0003 | |
| 2017-01173 | |
| 2020-03431 |