Molecular transition moments at large internuclear distances

X. Chu, A. Dalgarno

Research output: Contribution to journalArticlepeer-review

Abstract

The behavior of the dipole moments of molecular transitions is analyzed as a function of the internuclear distance R and it is shown that for allowed transitions the departure of the dipole moment from the value for the unperturbed atom varies as [Formula Presented] with a coefficient that can be obtained from the dynamic polarizability of one atom evaluated at the unperturbed transition frequency of the other.

Original languageEnglish
Article number024701
Pages (from-to)024701/1-024701/3
JournalPhysical Review A - Atomic, Molecular, and Optical Physics
Volume66
Issue number2
DOIs
StatePublished - Aug 2002

Fingerprint

Dive into the research topics of 'Molecular transition moments at large internuclear distances'. Together they form a unique fingerprint.

Cite this