Solution and solid-phase halogen and C-H hydrogen bonding to perrhenate

Casey J. Massena, Asia Marie S. Riel, George F. Neuhaus, Daniel A. Decato, Orion B. Berryman

Research output: Contribution to journalArticlepeer-review

40 Scopus citations

Abstract

1H NMR spectroscopic and X-ray crystallographic investigations of a 1,3-bis(4-ethynyl-3-iodopyridinium)benzene scaffold with perrhenate reveal strong halogen bonding in solution, and bidentate association in the solid state. A nearly isostructural host molecule demonstrates significant C-H hydrogen bonding to perrhenate in the same phases.

Original languageEnglish
Pages (from-to)1417-1420
Number of pages4
JournalChemical Communications
Volume51
Issue number8
DOIs
StatePublished - Jan 28 2015

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