Solution and solid-phase halogen and C-H hydrogen bonding to perrhenate

Casey J. Massena; Asia Marie S. Riel; George F. Neuhaus; Daniel A. Decato; Orion B. Berryman

doi:10.1039/c4cc09242b

Solution and solid-phase halogen and C-H hydrogen bonding to perrhenate

Casey J. Massena, Asia Marie S. Riel, George F. Neuhaus, Daniel A. Decato, Orion B. Berryman

Chemistry

University of Montana

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

¹H NMR spectroscopic and X-ray crystallographic investigations of a 1,3-bis(4-ethynyl-3-iodopyridinium)benzene scaffold with perrhenate reveal strong halogen bonding in solution, and bidentate association in the solid state. A nearly isostructural host molecule demonstrates significant C-H hydrogen bonding to perrhenate in the same phases.

Original language	English
Pages (from-to)	1417-1420
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	8
DOIs	https://doi.org/10.1039/c4cc09242b
State	Published - Jan 28 2015

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title = "Solution and solid-phase halogen and C-H hydrogen bonding to perrhenate",

abstract = "1H NMR spectroscopic and X-ray crystallographic investigations of a 1,3-bis(4-ethynyl-3-iodopyridinium)benzene scaffold with perrhenate reveal strong halogen bonding in solution, and bidentate association in the solid state. A nearly isostructural host molecule demonstrates significant C-H hydrogen bonding to perrhenate in the same phases.",

author = "Massena, {Casey J.} and Riel, {Asia Marie S.} and Neuhaus, {George F.} and Decato, {Daniel A.} and Berryman, {Orion B.}",

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AU - Massena, Casey J.

AU - Riel, Asia Marie S.

AU - Neuhaus, George F.

AU - Decato, Daniel A.

AU - Berryman, Orion B.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2015/1/28

Y1 - 2015/1/28

N2 - 1H NMR spectroscopic and X-ray crystallographic investigations of a 1,3-bis(4-ethynyl-3-iodopyridinium)benzene scaffold with perrhenate reveal strong halogen bonding in solution, and bidentate association in the solid state. A nearly isostructural host molecule demonstrates significant C-H hydrogen bonding to perrhenate in the same phases.

AB - 1H NMR spectroscopic and X-ray crystallographic investigations of a 1,3-bis(4-ethynyl-3-iodopyridinium)benzene scaffold with perrhenate reveal strong halogen bonding in solution, and bidentate association in the solid state. A nearly isostructural host molecule demonstrates significant C-H hydrogen bonding to perrhenate in the same phases.

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DO - 10.1039/c4cc09242b

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JO - Chemical Communications

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Solution and solid-phase halogen and C-H hydrogen bonding to perrhenate

Abstract

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