Solvatochromism and fluorescence response of a halogen bonding anion receptor

Jiyu Sun; Asia Marie S. Riel; Orion B. Berryman

doi:10.1039/c8nj00558c

Solvatochromism and fluorescence response of a halogen bonding anion receptor

Jiyu Sun
, Asia Marie S. Riel
, Orion B. Berryman

Chemistry and Biochemistry

University of Montana

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Herein, we present two 2,6-bis(4-ethynylpyridinyl)-4-fluoroaniline receptors that display solvatochromic absorption and emission. Neutral derivatives displayed opposite solvatochromic behavior as compared to the alkylated receptors. Adding anions induced changes in the absorption and emission spectra. In general, the fluorescence of the halogen bonding receptor was quenched less efficiently when compared to the hydrogen bonding receptor.

Original language	English
Pages (from-to)	10489-10492
Number of pages	4
Journal	New Journal of Chemistry
Volume	42
Issue number	13
DOIs	https://doi.org/10.1039/c8nj00558c
State	Published - 2018

Funding

This work was funded by National Science Foundation (NSF) CAREER CHE-1555324, the Center for Biomolecular Structure and Dynamics CoBRE (NIH NIGMS grant P20GM103546) and the University of Montana (UM). We would like to thank the anonymous reviewers for their insightful comments and suggestions.

Funder number
P20GM103546
CHE-1555324

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10.1039/c8nj00558c

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title = "Solvatochromism and fluorescence response of a halogen bonding anion receptor",

abstract = "Herein, we present two 2,6-bis(4-ethynylpyridinyl)-4-fluoroaniline receptors that display solvatochromic absorption and emission. Neutral derivatives displayed opposite solvatochromic behavior as compared to the alkylated receptors. Adding anions induced changes in the absorption and emission spectra. In general, the fluorescence of the halogen bonding receptor was quenched less efficiently when compared to the hydrogen bonding receptor.",

author = "Jiyu Sun and Riel, \{Asia Marie S.\} and Berryman, \{Orion B.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.",

year = "2018",

doi = "10.1039/c8nj00558c",

language = "English",

volume = "42",

pages = "10489--10492",

journal = "New Journal of Chemistry",

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publisher = "Royal Society of Chemistry",

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T1 - Solvatochromism and fluorescence response of a halogen bonding anion receptor

AU - Sun, Jiyu

AU - Riel, Asia Marie S.

AU - Berryman, Orion B.

PY - 2018

Y1 - 2018

N2 - Herein, we present two 2,6-bis(4-ethynylpyridinyl)-4-fluoroaniline receptors that display solvatochromic absorption and emission. Neutral derivatives displayed opposite solvatochromic behavior as compared to the alkylated receptors. Adding anions induced changes in the absorption and emission spectra. In general, the fluorescence of the halogen bonding receptor was quenched less efficiently when compared to the hydrogen bonding receptor.

AB - Herein, we present two 2,6-bis(4-ethynylpyridinyl)-4-fluoroaniline receptors that display solvatochromic absorption and emission. Neutral derivatives displayed opposite solvatochromic behavior as compared to the alkylated receptors. Adding anions induced changes in the absorption and emission spectra. In general, the fluorescence of the halogen bonding receptor was quenched less efficiently when compared to the hydrogen bonding receptor.

UR - https://www.scopus.com/pages/publications/85049231942

U2 - 10.1039/c8nj00558c

DO - 10.1039/c8nj00558c

M3 - Article

AN - SCOPUS:85049231942

SN - 1144-0546

VL - 42

SP - 10489

EP - 10492

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 13

ER -

Solvatochromism and fluorescence response of a halogen bonding anion receptor

Abstract

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