Structural and computational characterization of a bridging zwitterionic-amidoxime uranyl complex

Daniel A. Decato, Orion B. Berryman

Research output: Contribution to journalArticlepeer-review

Abstract

A bridging (μ2) neutral zwitterionic amidoxime binding mode previously unobserved between amidoximes and uranyl is reported and compared to other uranyl amidoxime complexes. Density functional theory computations show the dinuclear complex exhibits a shallow potential energy surface allowing for facile inclusion of a nonbonding water molecule in the solid-state.

Original languageEnglish
Pages (from-to)1038-1043
Number of pages6
JournalOrganic Chemistry Frontiers
Volume6
Issue number7
DOIs
StatePublished - Apr 7 2019

Fingerprint

Dive into the research topics of 'Structural and computational characterization of a bridging zwitterionic-amidoxime uranyl complex'. Together they form a unique fingerprint.

Cite this