@article{f6051421958b4812bc0b8a746f6d73df,
title = "Synthesis and characterization of pyridine- and thiophene-based platinacyclynes",
abstract = "Seven heterocyclic macrocycles, including the first platinacycles with pyridine and thiophene rings incorporated into the cyclyne system, are reported. Pt-acetylide cyclynes were assembled via tin transmetallation or amine-mediated oxidative addition with stoichiometric PtCl2(PEt3) 2 and CuI. The organometallic cyclynes exhibited enhanced electronic properties compared to previously described platinabenzocyclynes.",
keywords = "Acetylide, Benzocyclyne, Heterocycle, Metallacycle, Platinum(II)",
author = "Johnson, \{Charles A.\} and Baker, \{Benjamin A.\} and Berryman, \{Orion B.\} and Zakharov, \{Lev N.\} and O'Connor, \{Matthew J.\} and Haley, \{Michael M.\}",
note = "Funding Information: This research has been supported by the National Science Foundation (CHE-0414175). C.A.J. acknowledges the NSF for an IGERT fellowship. The CCD diffractometer was purchased with funds provided by the NSF (CHE-0234965). We thank Elisabeth Rather Healey for her initial work on the X-ray structure of 6 .",
year = "2006",
month = jan,
day = "15",
doi = "10.1016/j.jorganchem.2005.09.008",
language = "English",
volume = "691",
pages = "413--421",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier B.V.",
number = "3",
}