Synthesis of a beta-turn forming depsipeptide for hydrogen bond mediated electron transfer studies

David A. Williamson, Bruce E. Bowler

Research output: Contribution to journalArticlepeer-review

Abstract

Hydrogen bonds are believed to play an important role in the mediation of electron transfer processes in proteins. A porphyrin/depsipeptide/p-benzoquinone molecule has been synthesized to help understand this role of hydrogen bond mediated electron transfer in proteins. The synthesis, room temperature folding conformation, and steady-state electron transfer are described.

Original languageEnglish
Pages (from-to)12357-12372
Number of pages16
JournalTetrahedron
Volume52
Issue number38
DOIs
StatePublished - Sep 16 1996

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