Synthesis of new lipophilic acyclic di-ionizable polyethers, bis(crown ethers) and macrocyclic diamides

Sadik Elshani; Chien M. Wai; N. R. Natale; Richard A. Bartsch

doi:10.1016/S0040-4020(99)00514-1

Synthesis of new lipophilic acyclic di-ionizable polyethers, bis(crown ethers) and macrocyclic diamides

Sadik Elshani, Chien M. Wai, N. R. Natale, Richard A. Bartsch

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A series of new lipophilic acyclic polyethers containing two carboxylic or hydroxamic acid groups have been prepared. From lipophilic acyclic polyether dicarboxylic acids 2, 9 and 13, the bis(crown ethers) 20-25 were synthesized. From lipophilic acyclic polyether dicarboxylic acids 10-12 and 14, the new macrocyclic diamides 26-32 were prepared in high yields without the use of high dilution techniques or template effects.

Original language	English
Pages (from-to)	9425-9438
Number of pages	14
Journal	Tetrahedron
Volume	55
Issue number	31
DOIs	https://doi.org/10.1016/S0040-4020(99)00514-1
State	Published - Jul 30 1999

Funding

A¢lmowledgmeat. The research conducted at the University of Idaho was supported by the National Science Foundation's EPSCoR Program, Grant #Rll-8902065. The research performed at Texas Tech University was supported by the Division of Chemical Sciences of the Office of Basic Energy Sciences of the U.S. Department of Energy (Grant DE-FG03-94ER14416). We thank Dr. Hong-Sik Hwang for providing the sym-(amino)dibenzo-16-crown-5 (42).

Funder number
-8902065
DE-FG03-94ER14416

Keywords

Crown ethers
Host molecules
Macrocycles
Podands

Access to Document

10.1016/S0040-4020(99)00514-1

Cite this

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title = "Synthesis of new lipophilic acyclic di-ionizable polyethers, bis(crown ethers) and macrocyclic diamides",

abstract = "A series of new lipophilic acyclic polyethers containing two carboxylic or hydroxamic acid groups have been prepared. From lipophilic acyclic polyether dicarboxylic acids 2, 9 and 13, the bis(crown ethers) 20-25 were synthesized. From lipophilic acyclic polyether dicarboxylic acids 10-12 and 14, the new macrocyclic diamides 26-32 were prepared in high yields without the use of high dilution techniques or template effects.",

keywords = "Crown ethers, Host molecules, Macrocycles, Podands",

author = "Sadik Elshani and Wai, \{Chien M.\} and Natale, \{N. R.\} and Bartsch, \{Richard A.\}",

note = "Funding Information: A¢lmowledgmeat. The research conducted at the University of Idaho was supported by the National Science Foundation's EPSCoR Program, Grant \#Rll-8902065. The research performed at Texas Tech University was supported by the Division of Chemical Sciences of the Office of Basic Energy Sciences of the U.S. Department of Energy (Grant DE-FG03-94ER14416). We thank Dr. Hong-Sik Hwang for providing the sym-(amino)dibenzo-16-crown-5 (42).",

year = "1999",

month = jul,

day = "30",

doi = "10.1016/S0040-4020(99)00514-1",

language = "English",

volume = "55",

pages = "9425--9438",

journal = "Tetrahedron",

issn = "0040-4020",

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number = "31",

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TY - JOUR

T1 - Synthesis of new lipophilic acyclic di-ionizable polyethers, bis(crown ethers) and macrocyclic diamides

AU - Elshani, Sadik

AU - Wai, Chien M.

AU - Natale, N. R.

AU - Bartsch, Richard A.

N1 - Funding Information: A¢lmowledgmeat. The research conducted at the University of Idaho was supported by the National Science Foundation's EPSCoR Program, Grant #Rll-8902065. The research performed at Texas Tech University was supported by the Division of Chemical Sciences of the Office of Basic Energy Sciences of the U.S. Department of Energy (Grant DE-FG03-94ER14416). We thank Dr. Hong-Sik Hwang for providing the sym-(amino)dibenzo-16-crown-5 (42).

PY - 1999/7/30

Y1 - 1999/7/30

N2 - A series of new lipophilic acyclic polyethers containing two carboxylic or hydroxamic acid groups have been prepared. From lipophilic acyclic polyether dicarboxylic acids 2, 9 and 13, the bis(crown ethers) 20-25 were synthesized. From lipophilic acyclic polyether dicarboxylic acids 10-12 and 14, the new macrocyclic diamides 26-32 were prepared in high yields without the use of high dilution techniques or template effects.

AB - A series of new lipophilic acyclic polyethers containing two carboxylic or hydroxamic acid groups have been prepared. From lipophilic acyclic polyether dicarboxylic acids 2, 9 and 13, the bis(crown ethers) 20-25 were synthesized. From lipophilic acyclic polyether dicarboxylic acids 10-12 and 14, the new macrocyclic diamides 26-32 were prepared in high yields without the use of high dilution techniques or template effects.

KW - Crown ethers

KW - Host molecules

KW - Macrocycles

KW - Podands

UR - https://www.scopus.com/pages/publications/0033618526

U2 - 10.1016/S0040-4020(99)00514-1

DO - 10.1016/S0040-4020(99)00514-1

M3 - Article

AN - SCOPUS:0033618526

SN - 0040-4020

VL - 55

SP - 9425

EP - 9438

JO - Tetrahedron

JF - Tetrahedron

IS - 31

ER -

Synthesis of new lipophilic acyclic di-ionizable polyethers, bis(crown ethers) and macrocyclic diamides

Abstract

Funding

Keywords

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