The Asbestinins, a Novel Class of Diterpenes from the Gorgonian Briareum asbestinum

Donald B. Stierle; Brad Carté; D. John Faulkner; Bruce Tagle; Jon Clardy

doi:10.1021/ja00535a047

The Asbestinins, a Novel Class of Diterpenes from the Gorgonian Briareum asbestinum

Donald B. Stierle, Brad Carté, D. John Faulkner, Bruce Tagle, Jon Clardy

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Abstract

The gorgonian Briareum asbestinum contained two classes of diterpenes, the briareins and the asbestinins. The structure of asbestinh}-1 (3) was determined from a single-crystal X-ray diffraction study on the corresponding diol 8. The structures of asbestinins-2, -3, -4, and -5 (4-7) were determined by analysis of spectral data. The relationships between asbestinins-2,-3, -4, and -5 (4-7) and asbestinin-1 (3) were confirmed by chemical interconversions.

Original language	English
Pages (from-to)	5088-5092
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	102
Issue number	15
DOIs	https://doi.org/10.1021/ja00535a047
State	Published - Jul 1980

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title = "The Asbestinins, a Novel Class of Diterpenes from the Gorgonian Briareum asbestinum",

abstract = "The gorgonian Briareum asbestinum contained two classes of diterpenes, the briareins and the asbestinins. The structure of asbestinh}-1 (3) was determined from a single-crystal X-ray diffraction study on the corresponding diol 8. The structures of asbestinins-2, -3, -4, and -5 (4-7) were determined by analysis of spectral data. The relationships between asbestinins-2,-3, -4, and -5 (4-7) and asbestinin-1 (3) were confirmed by chemical interconversions.",

author = "Stierle, {Donald B.} and Brad Cart{\'e} and Faulkner, {D. John} and Bruce Tagle and Jon Clardy",

year = "1980",

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T1 - The Asbestinins, a Novel Class of Diterpenes from the Gorgonian Briareum asbestinum

AU - Stierle, Donald B.

AU - Carté, Brad

AU - Faulkner, D. John

AU - Tagle, Bruce

AU - Clardy, Jon

PY - 1980/7

Y1 - 1980/7

N2 - The gorgonian Briareum asbestinum contained two classes of diterpenes, the briareins and the asbestinins. The structure of asbestinh}-1 (3) was determined from a single-crystal X-ray diffraction study on the corresponding diol 8. The structures of asbestinins-2, -3, -4, and -5 (4-7) were determined by analysis of spectral data. The relationships between asbestinins-2,-3, -4, and -5 (4-7) and asbestinin-1 (3) were confirmed by chemical interconversions.

AB - The gorgonian Briareum asbestinum contained two classes of diterpenes, the briareins and the asbestinins. The structure of asbestinh}-1 (3) was determined from a single-crystal X-ray diffraction study on the corresponding diol 8. The structures of asbestinins-2, -3, -4, and -5 (4-7) were determined by analysis of spectral data. The relationships between asbestinins-2,-3, -4, and -5 (4-7) and asbestinin-1 (3) were confirmed by chemical interconversions.

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U2 - 10.1021/ja00535a047

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 15

ER -

The Asbestinins, a Novel Class of Diterpenes from the Gorgonian Briareum asbestinum

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