Trace gas emissions from laboratory biomass fires measured by open-path Fourier transform infrared spectroscopy: Fires in grass and surface fuels

The trace gas emissions from six biomass fires, including three grass fires, were measured using a Fourier transform infrared (FTIR) spectrometer coupled to an open-path, multipass cell (OP-FTIR). The quantified emissions consisted of carbon dioxide, nitric oxide, water vapor, carbon monoxide, methane, ammonia, ethylene, acetylene, isobutene, methanol, acetic acid, formic acid, formaldehyde, and hydroxyacetaldehyde. By including grass fires in this study we have now measured smoke composition from fires in each major vegetation class. The emission ratios of the oxygenated compounds, formaldehyde, methanol, and acetic acid, were 1-2% of CO in the grass fires, similar to our other laboratory and field measurements but significantly higher than in some other studies. These oxygenated compounds are important, as they affect O₃ and HO_x chemistry in both biomass fire plumes and the free troposphere. The OP-FTIR data and the simultaneously collected canister data indicated that the dominant C₄ emission was isobutene (C₄H₈) and not 1-butene. The rate constant for the reaction of isobutene with the OH radical is 60% larger than that of 1-butene. We estimate that 67±9% of the fuel nitrogen was volatilized with the major nitrogen emissions, ammonia, and nitric oxide, accounting for 22±8%.